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Questions

Question 1

What is the H—O—H bond angle in a water molecule, as stated in the text?

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Question 2

What is the approximate bond dissociation energy for a hydrogen bond in liquid water?

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Question 3

Which term describes compounds that are poorly soluble in water because they cannot form energetically favorable interactions with water molecules?

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Question 4

What is the primary thermodynamic driving force for the aggregation of nonpolar compounds in aqueous solution?

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Question 5

What is the value for the ion product of water, Kw, at 25 degrees Celsius?

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Question 6

What is the pH of a solution with an H+ concentration of 1.3 x 10^-4 M?

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Question 7

According to the titration curve for acetic acid (pKa = 4.76), in what state is the acid at the midpoint of the titration?

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Question 8

Which of the following pairs represents a conjugate acid-base pair?

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Question 9

What is the primary buffer system that acts in the cytoplasm of all cells?

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Question 10

What is the pKa of the phosphate buffer system (H2PO4-/HPO4^2-), making it an effective buffer in biological fluids?

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Question 11

In untreated diabetes mellitus, the accumulation of which two carboxylic acids can lead to a life-threatening condition called acidosis?

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Question 12

The formation of ATP from ADP and inorganic phosphate is an example of what type of reaction where the elements of water are eliminated?

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Question 13

What is the pH of a mixture of 0.042 M NaH2PO4 and 0.058 M Na2HPO4, given that the pKa is 6.86?

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Question 14

What is the 'apparent pKa' or pKcombined for the bicarbonate buffer system in clinical medicine, which accounts for the reservoir of CO2(d)?

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Question 15

What term describes the properties of water, such as vapor pressure and boiling point, that are altered by the presence of solutes?

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Question 16

How do hydrogen bonds in ice differ from those in liquid water at room temperature?

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Question 17

What is the van't Hoff factor (i) for a nonionizing solute like glucose?

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Question 18

The buffering range of a weak acid and its conjugate base generally extends about how many pH units on either side of its pKa?

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Question 19

What is the term for a solution that has a higher osmolarity than that of a cell's cytosol, causing the cell to shrink?

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Question 20

Hydrogen bonds are strongest and most stable when the hydrogen atom and the two atoms that share it are oriented in what way?

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Question 21

What is the concentration of H+ in a solution of 0.1 M NaOH?

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Question 22

A reaction that involves the cleavage of a bond accompanied by the addition of the elements of water is known as what?

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Question 23

Why do macromolecules like proteins and polysaccharides have less effect on the osmolarity of a solution than an equal mass of their monomeric components?

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Question 24

What is the dielectric constant of water at 25 degrees Celsius, which allows it to effectively screen electrostatic interactions between dissolved ions?

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Question 25

In a solution of a weak acid, if the pH is two units below its pKa, what is the approximate ratio of the conjugate base [A-] to the weak acid [HA]?

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